Gan substrate to fabricate a heterostructured microlaser diode and the electrically pumped wgm lasing from the diode is realized. Novel method for reclaimreuse of bulk gan substrates. Open access is an initiative that aims to make scientific research freely available to all. The fabrication of white lightemitting diodes using the n. Growth of gan on zno for solid state lighting applications. Gan was grown on zno buffered csapphire cal 2o 3 substrates by metal organic vapor phase epitaxy. Gan was grown on znobuffered csapphire cal 2 o 3 substrates by metal organic vapor phase epitaxy. Nano express open access fabrication and properties of. The zno then served as a sacrificial release layer, allowing chemical liftoff of the gan from the cal 2 o 3 substrate via selective wet etching of the zno. The alingan and zno materials systems have proven to be one of the scientifically and. Ganbased metaloxidesemiconductor devices intechopen. The structure, surface morphology, composition, and optical properties of these thin films were investigated by xray diffraction, field emission scanning electron microscopy, infrared absorption. Gan and znobased materials and devices stephen pearton.
Very high quality what used to be called whiskers and platelets, the nomenclature for which gave. The two wide band gap dilute magnetic semiconductors dms gd. Show full abstract first algan cladfree ganbased laser diodes, and progress in blue, green, and yellow emitters and report on the first demonstration of a normallyoff nonpolar ganbased. Scanning electron microscopy have well demonstrated the arrays of the zno nanorods and the proper etching into the nanotubes. Onedimensional zno nanostructures have great potential applications in the fields of optoelectronic and sensor devices. Ganbased lightemitting diode with zno nanotexture layer. Gan and znobased materials and devices springerlink. This content was uploaded by our users and we assume good faith they have the permission to share this book. Impurity contamination of gan epitaxial films from the. Spie 10533, oxide based materials and devices ix, 105332q 23 february 2018. Gan and znobased materials and devices pdf free download. The pace of advances in these areas has been remarkable and the wide band gap community relies on. Gan and znobased materials and devices springer series. Since mocvd is the dominant growth technology for ganbased materials and devices, there is a need to more fully explore this technique for zno substrates.
Using this approach, in gan based devices can be liftedoff expensive single crystal substrates and bonded onto supports with a better costperformance profile. Gan and znobased materials and devices springer series in. Process development for znobased devices by kelly pui sze ip a dissertation presented to the graduate school of the university of florida in partial fulfillment of the requirements for the degree of. It begins with an overview on basics of semiconductor materials, physics, growth and characterization techniques, followed by detailed discussion of advantages, drawbacks, design issues, processing, applications, and key challenges for state of the art gan based devices.
Zno exhibits better radiation resistance than gan for possible devices used in space and nuclear applications 22. Building on these possibilities, this paper further investigates the incorporation of zno as both an alternative buffer layer and a top contact epilayer for gan technology. Novel method for reclaimreuse of bulk gan substrates using. Besides these established applications, zno and its ternary alloys are now also being considered as potential materials for. Gan was grown on znobuffered csapphire cal 2o 3 substrates by metal organic vapor phase epitaxy.
Figure 1a shows that the reflection peaks of 100, 002, and 101 correspond to hexagonal zno with a wurtzite structure, but a preferred orientation along the 002 plane is intense. The nanostructured zno material has many applications in the area of nano based devices. The main objective of this thesis is not only to fabricate zno nrspgan, or zno nanotubes zntspgan heterostructures, but also to investigate their. Herein, we have developed heterojunction leds based on the wellaligned zno nanorods and nanotubes on the ptype gan with the insertion of the nio buffer layer that showed enhancement in the light emission. The alingan and zno materials systems have proven to be one of the. Quarterwafer areas of gan were removed from the gan substrate by selective chemical etching away of the zno interlayer. On the irst fpart of the dissertation, the synthesis of zno nanorod array via the low temperature solution growth method on flexible in 2o 3pet and rigid itoglass substrates were discussed.
We develop cuttingedge technologies and perform advanced research on iiinitride materials and devices. The roomtemperature electron hall mobility in singlecrystal zno is 200 cm2 v1, slightly lower than that of gan, but zno has higher saturation velocity. Synthesis and characterization of zno nanostructures. American journal of nano research and applications. Zno are among the most favored materials for spintronic applications. To date our community has made over 100 million downloads. Patterned growth of vertically aligned zno nanowire arrays on. Read book gan and znobased materials and devices springer. Download electrical characterization of silicononinsulator materials and. Even though research focusing on zno goes back many decades, the renewed interest is fueled by availability of highquality.
Structure, microstructure and physical properties of zno. Ultrathin aligned zno nanorod arrays grown by a novel diffusive pulsed laser deposition method pgan heterojunction device grown by mocvd structural and magnetic study of hardsoft systems with zno barrier grown by pulsed laser deposition. Electroluminescence from a zno homojunction device grown by. Growth and characterization of zno based semiconductor. As phd students, we found it difficult to access the research we needed, so we decided to create a new open access publisher that levels the playing field for scientists. The quantum efficiency qe of photoluminescence pl has been estimated in gan and zno samples. We investigate the electronic and magnetic properties of ganzno nanoribbons with density functional theory methods. The zno then served as a sacrificial release layer, allowing chemical liftoff of the gan from the cal 2o 3 substrate via selective wet etching of the zno.
Gan and zno are important semiconductor materials with applications in blue and ultraviolet. Zno along with gan has attracted intense attention in the search for hight c ferromagnetic diluted magnetic semiconductor dms materials, since dietls prediction that gan and zno based dms systems could exhibit ferromagnetism above room temperature upon doping with transition elements such as mn. The obtained large binding energies suggest that these graphitic nanostructures are stable and can hence be effectively synthesized. Novel znobased ternary oxides for optoelectronic applications. Zno, gan, atomic layer deposition, microbolometer, thin film transistor. Show full abstract first algan cladfree gan based laser diodes, and progress in blue, green, and yellow emitters and report on the first demonstration of a normallyoff nonpolar gan based. Supporting information band gap tailoring and visiblelightdriven photocatalytic performance of porous gan1 xznox solid solution aimin wu,a jing li,a,b baodan liu,b, wenjin yang,b yanan jiang,b lusheng liu,b xinglai zhang,b changmin xiong,c,xin jiangb, akey laboratory of materials modification by laser, ion, and electron beams. Shubra singh 1,2,3, p thiyagarajan 1,2, k mohan kant 1,2, d anita 1,2, s thirupathiah 1,2, n rama 1,2, brajesh tiwari 1,2, m kottaisamy 2 and m s ramachandra rao 1,2,3.
Read gan and znobased materials and devices springer series in materials science. In fact, gan can be the core nanostructures for led, 16 piezotronics,6,10 12 and even piezophotonics. Proposed devices are believed to pave the way for the ganbased stable flexibletransparent electronics after further materials and process optimization. There is, however, only one report on the gedoped zinc oxide films. Gallium nitride nanowire based nanogenerators and light. The heterojunction leds of zno nrspgan are best choice to take the advantage of gan ideal bluelight emission and fabricated leds explore the potential of white leds with superior performance. Handbook of gan semiconductor materials and devices crc.
The expensive gan substrates were then reclaimedreused without the need for polishing for a second cycle of zno and gan growth, which gave similar xrd, sem, cl and afm results to the first cycle. Challenges and opportunities in gan and zno devices and materials. The nanostructured materials have unique properties and the devices employing the nanostructures show superior performances when compared with the conventional devices without the. Dilute magnetic semiconductors based on gan and zno. In oxidebased materials and devices v 898719 proceedings of spie the international society for optical engineering.
Zinc oxide zno has been used in a wide range of products for many years, including, among others, varistors, surface acoustic wave devices and cosmetics. Scientific reports, issn 20452322, eissn 20452322, vol. This first systematic, authoritative and thorough treatment in one comprehensive volume presents the fundamentals and technologies of the topic, elucidating all aspects of zno materials and devices. Wurtzite zinc oxide wzno is a wide bandgap semiconductor that holds promise in power electronics applications, where heat dissipation is of critical importance. The whispering gallery mode wgm lasing and microphotoluminescence from a hexagonal zno microrod are investigated. Patterned growth of vertically aligned zno nanowire arrays. Gan and znobased materials and devices by stephen pearton. Zno films were deposited on indium tin oxide ito, which formed the transparent conductive layer tcl of a ganbased lightemitting diode led, by ultrasonic spraying pyrolysis to increase the light output power. The semiconductor zno has gained substantial interest in the research community in part because of its large exciton binding energy 60 mev which could lead to lasing action based on exciton recombination even above room temperature. High quantum efficiency of photoluminescence in gan and zno. The zno nanotexture was formed by treating the asdeposited zno films with hydrogen. Pdf challenges and opportunities in gan and zno devices and. Likely contamination of gan films by impurities emanating from al 2 o 3, sic and zno substrates during growth has been studied by secondary ion mass spectrometry analysis the highly defective interfacial region allows impurities to incorporate more readily as comparedjo the equilibrium solubility in a perfect crystal at a given temperature as evidenced by increased impurity levels in that.
A dissertation submitted in partial fulfillment of the requirements. Recombination via the shallow donoracceptor pair transitions dominated in this sample. The alingan and zno materials systems have proven to be one of the scientifically and technologically important areas of development over the past 15 years, with applications in uvvisible optoelectronics and in highpowerhighfrequency microwave devices. Spie 10533, oxidebased materials and devices ix, 105332q 23 february 2018. Review of ganzno hybrid structures based materials and. In the past two decades, the heteroepitaxy of gan q. Proposed devices are believed to pave the way for the gan based stable flexibletransparent electronics after further materials and process optimization. Likely contamination of gan films by impurities emanating from al 2 o 3, sic and zno substrates during growth has been studied by secondary ion mass spectrometry analysis. Gan was grown on zno buffered csapphire cal 2 o 3 substrates by metal organic vapor phase epitaxy. The commercial success of ganbased optoelectronic and electronic devices trig the interest in znobased devices 24.
The highly defective interfacial region allows impurities to incorporate more readily as comparedjo the equilibrium solubility in a perfect crystal at a given temperature as evidenced. Structure, microstructure and physical properties of zno based materials in various forms. Based in the department of electronic and electrical engineering at the university of sheffield we are keen to share research insights, build successful partnerships and strengthen links with industry and academia. A sidoped gan layer grown by molecular beam epitaxy mbe exhibited the highest qe of about 90% at low temperatures. The structure, surface morphology, composition, and optical properties of these thin films were investigated by xray diffraction, field emission scanning electron. Despite intense research efforts during the last years, the origin of the magnetic order is still under debate. Thermal conductivity of wurtzite zincoxide from first. Fabrication and characterization of zno and gan devices for. Novel process for direct bonding of gan onto glass substrates. The gan was subsequently directwaferbonded onto a glass substrate. The alingan and zno materials systems have proven to be one of the scientifically and technologically important areas of development over the past 15 years, with applications in uvvisible optoelectronics and in highpower highfrequency microwave devices. Pdf download information science for materials discovery and design.
Novel method for reclaimreuse of bulk gan substrates using sacrificial zno release layers. Review of gan zno hybrid structures based materials and devices. Following an introduction, the authors look at the general properties of zno, as well as its growth, optical processes, doping and zno based dilute. Fabrication and properties of znogan heterostructure. Characteristics of znobased semiconductor ceramics doped. Nano express open access fabrication and properties of zno. It begins with an overview on basics of semiconductor materials, physics, growth and characterization techniques, followed by detailed discussion of advantages, drawbacks, design issues, processing, applications, and key challenges for state of the art ganbased devices. Recent advances in zno materials and devices sciencedirect.
Study of gan based nanostructures and hybrids diva. Zno nanowirep gan heterojunction leds xinyu wang 1, jesse cole1, amir m. Structural property of znogan thin films figure 1a,b,c shows the xrd spectra of znosi, gansi, and znogansi films. Department of science and technology itn, campus norrkoping, linkoping university, se601 74 norrkoping, sweden. Their calculated properties strongly depend on the edge atomic configuration. Gan disable the use of this material in low temperature flexible. The research work presented in this dissertation is based on two direct and wide band gap semiconductors. The sources of radiative and nonradiative recombination in gan and zno are discussed. Han department of electrical engineering, yale university, 15 prospect street, bct 517, new haven, ct 06511, usa email. Its based on principles of collaboration, unobstructed discovery, and, most importantly, scientific progression. The lattice mismatch between the wurzite gan 0001 plane and wurzite zno 0001 plane is 1. Novel process for direct bonding of gan onto glass. Zno based diluted magnetic semiconductor may lead to devices with new and enhanced functionality, such as polarized solid state optical components, nonvolatile storage.
375 1091 1072 1283 108 1512 993 283 449 1418 1301 499 357 255 1098 1360 735 1183 719 750 401 995 644 1597 731 110 1134 1178 895 141 178 528 593 604 799 350 838 1262 939 1475 1273 600 453 829